ULTRA Loaded Resins Based on the Cross-Linking of Linear Poly(ethylene imine). Improving the Atom Economy of Polymer-Supported Chemistry J.R. gratefully acknowledges support from Prof. G. Jung and Prof. M. E. Maier, Tübingen, the Strukturfonds of the University of Tübingen, DFG project “Reactive Intermediates in Polymeric Gels” (Ra 895/2), the Fonds der Chemischen Industrie, and from the DFG graduate college “Chemistry in Interphases” (project 6, Rademann), from which M.B. receives a stipend. We are grateful to Rainer Fischer, Elke Gesele, Dr. Klaus Eichele, and Nicole Sessler for analytical and technical support. We thank Personal Chemistry GmbH, Constance, Germany, for lending us a microwave synthesizer.

Author(s):  
Jörg Rademann ◽  
Michael Barth
2014 ◽  
Vol 15 (4) ◽  
pp. 1124-1131 ◽  
Author(s):  
Christoph Englert ◽  
Lutz Tauhardt ◽  
Matthias Hartlieb ◽  
Kristian Kempe ◽  
Michael Gottschaldt ◽  
...  

2020 ◽  
Vol 10 (2) ◽  
pp. 290-296
Author(s):  
Fariba Hajifathaliha ◽  
Arash Mahboubi ◽  
Elham Mohit ◽  
Noushin Bolourchian ◽  
Vahid Khalaj ◽  
...  

Purpose: Poly l-lysine (PLL) has been introduced as a strengthening covering layer for alginate microcapsules which are the most convenient way for cell encapsulation. Some disadvantages of PLL such as high price and low biocompatibility have prompted scientists to find better alternatives. Linear poly ethylene imine (LPEI), thanks to its highly similar structure to PLL, could be considered as a proper cost-effective alternative. In this study LPEI and PLL were compared as covering layers of cell-loaded alginate-LPEI-alginate (cALA) and alginate-PLL-alginate (cAPA) microcapsules. Methods: In addition to the physico-mechanical properties, the encapsulation efficiency, cell survival post encapsulation, cell viability, and cellular metabolic activity within the microcapsules were evaluated using trypan blue, live/dead cell staining, and MTT test, respectively. Results: Physico-mechanical evaluation of the microcapsules revealed that the cell microencapsulation process did not affect their shape, size, and mechanical stability. Although the encapsulation efficiency for cALA and cAPA was not different (P>0.05), cell survival post encapsulation was higher in cALA than in cAPA (P<0.05) which could be the reason for the higher cell viability and also cellular metabolic activity within these microcapsules in comparison to cAPA. Conclusion: Here, based on these results, ALA could be introduced as a preferable alternative to APA for cell encapsulation.


2014 ◽  
Vol 113 ◽  
pp. 597-606 ◽  
Author(s):  
Sofia Ochrimenko ◽  
Antje Vollrath ◽  
Lutz Tauhardt ◽  
Kristian Kempe ◽  
Stephanie Schubert ◽  
...  

2011 ◽  
Vol 289 (8) ◽  
pp. 881-888 ◽  
Author(s):  
Andriy Shkilnyy ◽  
Stefanie Schöne ◽  
Claudia Rumplasch ◽  
Annett Uhlmann ◽  
Annett Hedderich ◽  
...  

2017 ◽  
Vol 8 (46) ◽  
pp. 7169-7179 ◽  
Author(s):  
Igor Perevyazko ◽  
Alexander S. Gubarev ◽  
Lutz Tauhardt ◽  
Anatoly Dobrodumov ◽  
Georges M. Pavlov ◽  
...  

In-depth characterization of pharmaceutically relevant polymers plays a pivotal role in many areas, including nanoscience, gene therapy, analytical and polymer chemistry etc.


Holzforschung ◽  
2011 ◽  
Vol 65 (3) ◽  
Author(s):  
Lars Passauer ◽  
Klaus Fischer ◽  
Falk Liebner

Abstract Highly swellable, mechanically stable hydrogels were obtained by cross-linking different technical lignins with poly(ethylene) glycol diglycidyl ether (PEGDGE). The gelation time and the properties of the products can be controlled by the extent of pre-oxidation and the cross-linking conditions, namely the dynamic viscosity η*, storage and loss modulus (G′; G″), and loss factor tan δ. The highest free swelling capacities (FSC) of up to 50 g water per g xerogel were obtained from pre-oxidized pine kraft lignin Indulin® AT and spruce organosolv lignin. Dynamic rheological measurements confirmed the typical rheological behaviour of gel structures, i.e. a linear decrease of dynamic viscosity about three orders of magnitude within a frequency range of 0.08 and 20 s-1. The results furthermore revealed a good mechanical sturdiness of the cross-linked lignin hydrogels. Sandy soils supplemented with small quantities of the hydrogels were found to feature a significantly increased plant-available water content. Based on the observed effects, oligo(oxyethylene) lignins are promising materials with respect to a prolonged water retention in soils.


2011 ◽  
Vol 115 (29) ◽  
pp. 9098-9105 ◽  
Author(s):  
Marco Finessi ◽  
Prashant Sinha ◽  
István Szilágyi ◽  
Ionel Popa ◽  
Plinio Maroni ◽  
...  

2010 ◽  
Vol 43 (2) ◽  
pp. 927-933 ◽  
Author(s):  
Hanneke M. L. Lambermont-Thijs ◽  
Friso S. van der Woerdt ◽  
Anja Baumgaertel ◽  
Lies Bonami ◽  
Filip E. Du Prez ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (72) ◽  
pp. 68371-68378 ◽  
Author(s):  
Zhen Liu ◽  
Shaojie Han ◽  
Chong Xu ◽  
Yuwen Luo ◽  
Na Peng ◽  
...  

A novel polymer binder, synthesized via in situ thermal cross-linking of water-soluble polyvinyl alcohol (PVA) and poly(ethylene imine) (PEI) precursor, is applied as a functional network binder to enhance the electrochemical performance of a silicon anode.


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